Hello, X!
Congratulations on getting the Prop Hunt Moderator role, I'll be guiding you through all the commands, so hopefully you will have understood all their functions and occasions when you should use them.

Chat commands: Tgag (for voice comms) and Tmute(for text chat comms) are both commands used for taking action against people that have either spammed the chat (regardless of VC or text) or have been disrespectful/offensive. Amute is for when someone is spamming the admin chat.

Webtauntmute/unmute is used for players that play offensive taunts.

Slay, as it says, slays a target.

Bring and the goto commands are for teleporting to someone or bringing them to you, used mainly to unstuck someone.

Kick, obviously kicks a target. Used to deal with players with offensive names/names that promote a non-ZARP service.

FSpec forces spectator mode on the target.

Friends checks whether the target is friends with anyone, this command is used as "starter" Ghosting evidence.

Checkspec checks who a target is spectating, this is also used for finding Ghosters.

Forceteam forces someone on any team you choose, this is for dealing with Ghosters.

That's about all the commands you should/can use, if you have any more questions or want a more detailed guide, contact me and I'll answer them all. Have a nice day!